Fire Safety in the Laboratory
Hazardous Chemical Spills/Releases
What should Lab Personnel
do in the event of a Hazardous Chemical Spill/Release?
What should
lab personnel do in case of contact with hazardous chemicals?
When a hazardous chemical is accidentally released,
immediately call EH&S at x4-8749. If anyone has been
injured and
medical attention is necessary, call Security at x99 for the Columbia
Area Volunteer Ambulance (CAVA) before calling EH&S to report
the
spill. After normal work hours and on weekends and University
holidays, report the incident to Security. Security will then
notify a member of EH&S. When reporting a spill or leak,
please
give as much detailed information as possible (location, chemical name,
how much was spilled, etc.). It is particularly important to
report the exact name of the chemical involved - spelling it out, if
necessary.
Do not attempt to clean up
a hazardous chemical spill yourself! You could be risking serious
injury. Laboratory personnel often do not have the proper
personal protective equipment (i.e., respirator) to clean up a
spill. In addition, it is a violation of Federal law to combat a
chemical spill without the proper emergency response training mandated
by the Occupational Safety and Health Administration (OSHA). When
a hazardous chemical is spilled, leave the area, close all doors to the
spill area, and report the incident to EH&S or Security.
If
laboratory personnel are accidentally splashed with hazardous
chemicals, it must be immediately removed from contact in order to
minimize injury. The only way to minimize or prevent personal
injury from chemical contact is to immediately remove the chemical by
drenching with massive amounts of water using the emergency shower,
located near the entrance of the lab. Drenching must continue for
at least 15 minutes. If you have been splashed with chemicals,
remove the chemical from contact first. Then notify
EH&S
or Security, or have someone else in the lab notify them. After
chemical contact, medical attention may also be necessary.
Go to Top
Fire Safety in the Laboratory
Large quantities of flammable liquids, solids, and gases, unstable/reactive
materials, together with energetic chemical reactions - make research
laboratories uniquely hazardous in terms of potential for fire.
However, historically, occurrence of laboratory fires has been
extremely rare, limited to a few small incidents that did not involve
negligence on the part of laboratory personnel.
In order to reduce/eliminate the potential for fire, observe and
enforce all FDNY regulations within your own laboratory. Pay particular
attention to the flammable storage limits for the different laboratory
types. Flammable storage limits are based on laboratory type, which
is based on fire rating/fire suppression of the lab. Flammable
storage limits are listed in the table below.
Lab type |
fire rating |
fire protection |
flammable liquids |
flammable solids |
oxidizing materials |
unstable reactive |
I |
2 hours |
Sprinklers |
30 gallons |
15 lbs |
50 lbs |
12 lbs |
II |
1 hour |
Sprinklers |
25 gallons |
10 lbs |
40 lbs |
6 lbs |
III |
2 hours |
No sprinklers |
20 gallons |
6 lbs |
30 lbs |
3 lbs |
IV |
1 hour |
No sprinklers |
15 gallons |
3 lbs |
20 lbs |
2 lbs |
At the entrance to each laboratory, the annual FDNY permit is
posted and the flammable limits for the lab type are listed. Please
do not exceed these storage/use limits. Fires can spread outside
a lab if the available fuel can sustain a fire longer than the
fire rating for the lab.
If a fire should ignite in your lab, and only if
you feel comfortable fighting a fire, you may attempt to put out
a small fire yourself. Know the locations of the fire extinguishers
in your lab. They are always highly visible and usually located
inside the entrance to the lab, at the ends of the benches, and
near the window ledges. If you are regularly working with flammable
metals, you may request a class D extinguisher for your lab.
Go to Top
When using a fire extinguisher, remember the word PASS:
Pull the pin
Aim the nozzle at the base of the fire
Squeeze the handle to release the extinguishing
agent
Sweep the base of the fire from side to side
If you attempt to fight the fire yourself, place yourself between
the fire and the exit so that you have a clear escape. DISCHARGE
ONLY ONE EXTINGUISHER. If the fire cannot be extinguished using
one extinguisher, do not search for another. Leave the room, closing
the (fire rated) door behind you.
Hazardous Chemical Spills/Releases
Laboratory personnel are not required to
clean up spills of hazardous chemicals. Indeed, EH&S strongly
discourages lab personnel from attempting to clean up
chemical spills. Remediation of chemical spills often requires
the use of personal protective equipment (respirators, protective
suits) that is never available to lab personnel.
Never work alone in a laboratory,
especially during times that are outside of “normal working
hours” (i.e., Monday – Friday, 9am – 5pm).
If you are accidentally splashed with chemicals, or if there
is a spill in your lab, you may require the immediate assistance
of a laboratory coworker.
Go to Top
What should Lab Personnel do in the event of a Hazardous
Chemical Spill/Release?
- During regular working hours (i.e.,
9am – 5pm, Monday – Friday): call EH&S
immediately (x4-8749). Give as much information as
possible: exact location
of spill, chemical name, and the amount spilled. Evacuate
all lab personnel from the room if the spill occurred outside
of a fume hood and close the door.
- At all other times: call Security
at x99, again, give as much information as possible
(exact location,
chemical name, amount of chemical spilled). Spell
out chemical names. Security will then coordinate
the response with EH&S personnel.
|
What should lab personnel do
in case of contact with hazardous chemicals?
- For skin or eye contact: immediately remove the
chemical from contact by flooding the area of contact with
copious amounts of water from the emergency shower or eyewash for
at least 15 minutes. RAPID REMOVAL FROM CONTACT
IS ABSOLUTELY CRITICAL TO MINIMIZING/PREVENTING CHEMICAL
INJURY!
- If chemical has been inhaled, move to fresh air.
- If chemical contact is minor (i.e.,
short duration of contact, small quantity, small area
of contact, and involving a low-hazard chemical), seek
medical attention at CU Health Services. Walk in (3 rd
floor, John Jay Hall) or call ahead (x4-2284). Give the
name of the chemical involved and bring along a Material
Safety Data Sheet for the chemical.
- If chemical contact is severe (i.e., involving
a high-hazard chemical; short duration,
small quantity, small area of contact – these factors
do not reliably predict severity when a high-hazard chemical
is involved), and is likely to result in more
serious health effects (whether immediate-onset or
delayed), contact Security at x99 to be transported
by ambulance to St. Luke’s – Roosevelt
Hospital Emergency Room. Remember, emergency medical
attention occurs after flooding
the area of contact with water from the emergency
shower or eyewash for at least 15 minutes. Ideally,
another lab member should call for medical assistance.
Prevention
of Hazardous Chemical Spills/Releases.
- Always work with chemicals inside a fume hood. In
the event of a spill (or, even during normal use),
chemical vapors will be contained.
- Store glass reagent containers in cabinets or on
shelves, never on the floor (reagent containers are
almost never plastic-coated by the manufacturer).
- Wherever practical, purchase reagents in smaller,
less unwieldy, quantities.
- Use secondary containment when transporting chemicals
on the elevator/dumbwaiter or through the hallways.
|
|